Chernyy, Sergey; Mahalik, Jyoti P.; Kumar, Rajeev; Kirkensgaard, Jacob Judas Kain; Arras, Matthias M. L.; Kim, Hyeyoung; Schulte, Lars; Ndoni, Sokol; Smith, Gregory S.; Mortensen, Kell; Sumpter, Bobby G.; Russell, Thomas P.; Almdal, Kristoffer
On the morphological behavior of ABC miktoarm stars containing poly(cis 1,4-isoprene), poly(styrene), and poly(2-vinylpyridine)
Fundamental understanding of microphase separation in ABC miktoarm copolymers is vital to access a plethora of nonconventional morphologies. Miktoarm stars based on poly(cis 1,4-isoprene) (I), poly(styrene) (S), and poly(2-vinylpyridine) (V) are model systems, which allow systematic studies of the effects of composition, chemical microstructure, and temperature on the thermodynamics of…
Investigating Particle Size Effects in Catalysis by Applying a Size-Controlled and Surfactant-Free Synthesis of Colloidal Nanoparticles in Alkaline Ethylene Glycol: Case Study of the Oxygen Reduction Reaction on Pt
Quinson, Jonathan; Inaba, Masanori; Neumann, Sarah; Swane, Andreas A.; Bucher, J.; Simonsen, Søren B.; Theil Kuhn, Luise; Kirkensgaard, Jacob J. K.; Jensen, Kirsten M. Ø.; Oezaslan, Mehtap; Kunz, Sebastian; Arenz, Matthias
Colloidal platinum nanoparticles are obtained via a surfactant-free polyol process in alkaline ethylene glycol. In this popular synthesis, ethylene glycol functions as solvent and reducing agent. The preparation procedure is known for its reproducibility to obtain 1–2 nm nanoparticles, but at the same time the controlled preparation of larger nanoparticles…
Overcoming efficiency and stability limits in water-processing nanoparticular organic photovoltaics by minimizing microstructure defects
Xie, Chen; Heumüller, Thomas; Gruber, Wolfgang; Tang, Xiaofeng; Classen, Andrej; Schuldes, Isabel; Bidwell, Matthew; Späth, Andreas; Fink, Rainer H.; Unruh, Tobias; McCulloch, Iain; Li, Ning; Brabec, Christoph J.
Water-based semiconducting polymer nanoparticles are eco-friendly and non-toxic but their performance suffers from the surfactants. Here Xie et al. design an approach to minimize the amount of residual surfactant in these nanoparticles and make high-efficiency and stability solar…
Poly(arylene alkylene)s with pendant N -spirocyclic quaternary ammonium cations for anion exchange membranes
Huong Pham, Thanh; S. Olsson, Joel; Jannasch, Patric
Journal of Materials Chemistry A, 2018, vol 6, 34, pp. 16537-16547DOI:10.1039/C8TA04699AVisit the full articleBack to the overview
Liquid crystal phantom for validation of microscopic diffusion anisotropy measurements on clinical MRI systems
Nilsson, Markus; Larsson, Johan; Lundberg, Dan; Szczepankiewicz, Filip; Witzel, Thomas; Westin, Carl-Fredrik; Bryskhe, Karin; Topgaard, Daniel
Purpose To develop a phantom for validating MRI pulse sequences and data processing methods to quantify microscopic diffusion anisotropy in the human brain. Methods Using a liquid crystal consisting of water, detergent, and hydrocarbon, we designed a 0.5-L spherical phantom showing the theoretically highest possible degree of microscopic anisotropy. Data…
Scalable, anisotropic transparent paper directly from wood for light management in solar cells
Jia, Chao; Li, Tian; Chen, Chaoji; Dai, Jiaqi; Kierzewski, Iain Michael; Song, Jianwei; Li, Yiju; Yang, Chunpeng; Wang, Chengwei; Hu, Liangbing
The growing demand for flexible electronics and solar energy conversion devices has fueled a search for high-quality paper-based materials with excellent mechanical flexibility and optical properties such as high transparency and haze. Despite the tremendous efforts have been dedicated to developing paper-based materials with high transparency or high haze, challenges…
Nanostructured antigen-responsive hydrogels based on peptides for leishmaniasis detection
Souza, Sivoney F.; Silva, Emerson R.; Alves, Wendel A.
Journal of the Brazilian Chemical Society, 2017, vol 28, 9, pp. 1619–1629 DOI: Back to the overview
Adduct modified nano-clay mineral dispersed polystyrene nanocomposites as advanced corrosion resistance coatings for aluminum alloys
Raju, Annu; Lakshmi, V.; Vishnu Prataap, R. K.; Resmi, V. G.; Rajan, T. P. D.; Pavithran, C.; Prasad, V. S.; Mohan, S.
The present investigation is on processing of a series of clay polystyrene nanocomposite (CPS) coatings containing different adduct modified montmorillonite (Mt) for corrosion resistance coating applications. The corrosion properties were studied using potentiodynamic and electrochemical impedance spectroscopy measurements in 3.5wt% aqueous NaCl electrolyte. The CPS coatings offered enhanced
Anomalies in the low frequency vibrational density of states for a polymer with intrinsic microporosity – the Boson peak of PIM-1
Zorn, Reiner; Yin, Huajie; Lohstroh, Wiebke; Harrison, Wayne; Budd, Peter M.; Pauw, Brian R.; Böhning, Martin; Schönhals, Andreas
Polymers with intrinsic microporosity are promising candidates for the active separation layer in gas separation membranes. Here, the vibrational density of states (VDOS) for PIM-1, the prototypical polymer with intrinsic microporosity, is investigated by means of inelastic neutron scattering. The results are compared to data measured for a more conventional…