Category

GIWAXS

(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOtherRenewable energyTechnique

Effect of Solvent Additives on the Morphology and Device Performance of Printed Nonfullerene Acceptor Based Organic Solar Cells

Wienhold, Kerstin S.; Körstgens, Volker; Grott, Sebastian; Jiang, Xinyu; Schwartzkopf, Matthias; Roth, Stephan V.; Müller-Buschbaum, Peter

Printing of active layers of high-efficiency organic solar cells and morphology control by processing with varying solvent additive concentrations are important to realize real-world use of bulk-heterojunction photovoltaics as it enables both up-scaling and optimization of the device performance. In this work, active layers of the conjugated polymer with benzodithiophene…
sergio.rodrigues@xenocs.com
12 March 2021
ApplicationCharacterizationCustomer publicationsGIWAXSInorganic materialInorganic materialsMaterialOtherOtherTechnique

Emergence of lead halide perovskite colloidal dispersions through aggregation and fragmentation: insights from the nanoscale to the mesoscale

Pratap, Shambhavi; Keller, Elisabeth; Müller-Buschbaum, Peter

The structural and optoelectronic properties of mixed halide perovskite colloidal precursor dispersions are investigated. With increasing concentration, we observe four stages of growing structures, which affect the thin film morphology: (I) nanoparticles, (II) increasing size of nanoparticles, (III) formation of large aggregates/complex clusters and (IV) fragmentation of large…
sergio.rodrigues@xenocs.com
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechniqueThin films

Surface modification of ZnO electron transport layers with glycine for efficient inverted non-fullerene polymer solar cells

Zhu, Xiaoqian; Guo, Bing; Fang, Jin; Zhai, Tianshu; Wang, Yanan; Li, Guangwei; Zhang, Jianqi; Wei, Zhixiang; Duhm, Steffen; Guo, Xia; Zhang, Maojie; Li, Yongfang

Interfacial engineering is crucial to improve the photovoltaic performance of polymer solar cells (PSCs). In this study, we demonstrate efficient inverted non-fullerene PSCs with ZnO modified by nontoxic glycine (Gly) as the electron transport layer (ETL). With the modification of Gly, work function of the ETL interlayer was decreased from…
sergio.rodrigues@xenocs.com
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisOtherSurface structure and patternsTechniqueThin films

Highly Ordered Semiconducting Polymer Arrays for Sensitive Photodetectors

Wei, Xiao; Gao, Hanfei; Feng, Jiangang; Pi, Yueyang; Zhang, Bo; Zhai, Yu; Wen, Wen; He, Mingqian; Matthews, James R.; Wang, Hongxiang; Li, Yang; Jiang, Shimei; Jiang, Lei; Wu, Yuchen

Semiconducting conjugated polymers possess attractive optoelectronic properties and low-cost solution processability and are inherently mechanically flexible. However, the device performance is susceptible to the fabrication methods because of the relatively weak intermolecular interaction of the polymers and their inherent conformational and energetic disorder. An efficient fabrication technique…
sergio.rodrigues@xenocs.com
12 March 2021
(Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsGIWAXSMaterialRenewable energySurface structure and patternsTechniqueThin films

Large Crystalline Domains and an Enhanced Exciton Diffusion Length Enable Efficient Organic Solar Cells

Zhang, Yiwei; Sajjad, Muhammad T.; Blaszczyk, Oskar; Parnell, Andrew J.; Ruseckas, Arvydas; Serrano, Luis A.; Cooke, Graeme; Samuel, Ifor D. W.

We studied crystallinity and exciton harvesting in bulk heterojunctions of the semiconducting polymer PffBT4T-2OD and electron acceptor PC71BM that are used to make highly efficient organic solar cells. Grazing incidence wide-angle X-ray scattering shows that the size of crystalline domains of PffBT4T-2OD increases to ?18 nm in photovoltaic blends upon…
sergio.rodrigues@xenocs.com
12 March 2021
(Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechniqueThin films

Overcoming the energy loss in asymmetrical non-fullerene acceptor-based polymer solar cells by halogenation of polymer donors

Fan, Qunping; Liu, Tao; Gao, Wei; Xiao, Yiqun; Wu, Jingnan; Su, Wenyan; Guo, Xia; Lu, Xinhui; Yang, Chuluo; Yan, He; Zhang, Maojie; Li, Yongfang

To achieve efficient polymer solar cells (PSCs), it is important to overcome the energy loss (Eloss) from the optical bandgap to the open-circuit voltage (Voc) of the device by properly matching donor/acceptor (D/A) photovoltaic materials. Here, we develop efficient PSCs based on the absorption complementary pairs of halogenated polymer donors…
sergio.rodrigues@xenocs.com
12 March 2021
ApplicationCharacteristic dimensionCharacterizationCustomer publicationsFractal dimensionGISAXSGIWAXSMaterialOrientation analysisRenewable energyTechniqueThin films

Enhanced gas barrier property of stacking-controlled reduced graphene oxide films for encapsulation of polymer solar cells

Sung, Sae Jin; Park, Jisoo; Cho, Young Shik; Gihm, Se Hoon; Yang, Seung Jae; Park, Chong Rae

Compact stacking of building blocks is essential in order to utilize the impermeable nature of reduced graphene oxide (rGO) for encapsulating barriers in organic electronics. To obtain the desired accumulation characteristic, rGO films were fabricated via spraying process using phase-controlled graphene oxide (GO) dispersion. The rGO laminate prepared from the…
sergio.rodrigues@xenocs.com
12 March 2021
(Natural) polymersApplicationCharacteristic dimensionCharacterizationCrystalline fractionCustomer publicationsGISAXSGIWAXSMaterialRenewable energySurface structure and patternsTechniqueThin films

Revisiting the Role of Graphene Quantum Dots in Ternary Organic Solar Cells: Insights into the Nanostructure Reconstruction and Effective Förster Resonance Energy Transfer

Sung, Sae Jin; Kim, Jae Ho; Gihm, Se Hoon; Park, Jisoo; Cho, Young Shik; Yang, Seung Jae; Park, Chong Rae

Recent studies have introduced the graphene quantum dot (GQD) as a third material for the bulk-heterojunction polymer:fullerene solar cell (PSC) to improve light conversion efficiency. Although exciton generation/dissociation and carrier transport in the GQD-incorporated light-absorbing layer are strongly influenced by the ternary component, detailed analysis on the role of GQD…
sergio.rodrigues@xenocs.com
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energyTechniqueThin films

Brønsted acid mediated covalent organic framework membranes for efficient molecular separation

Wang, Hongjian; Chen, Long; Yang, Hao; Wang, Meidi; Yang, Leixin; Du, Haiyan; Cao, Chenliang; Ren, Yanxiong; Wu, Yingzhen; Pan, Fusheng; Jiang, Zhongyi

Covalent organic frameworks (COFs) hold great promise in molecular separation. However, since the aperture size of most COFs is in the range of 0.8–4.9 nm, constructing COF membranes with a smaller aperture size is thus in urgent demand yet remains a grand challenge. In this study, a Brønsted acid mediated…
sergio.rodrigues@xenocs.com
12 March 2021