Inorganic materials

ApplicationCatalystsCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialOtherTechniqueWAXS

Synthesis, Modular Composition, and Electrochemical Properties of Lamellar Iron Sulfides

Horwitz, Noah E.; Shevchenko, Elena V.; Park, Jehee; Lee, Eungje; Xie, Jiaze; Filatov, Alexander S.; Anderson, John

Transition metal chalcogenides with layered structures have emerged as promising materials for energy storage, catalysis, and electronics, among other areas. We have identified a new layered phase of iron sulfide containing interlayer solvated cations. We present an optimized synthesis for the Li+-containing material from an Fe(III) xanthate complex. Structure and…
12 March 2021
ApplicationCharacterizationCustomer publicationsInorganic materialsOrientation analysisTechniqueWAXS

Macroscopic interpretation of nano-scale scattering data in clay

Birmpilis, G.; Ahmadi-Naghadeh, R.; Dijkstra, J.

The potential of X-ray scattering measurements for monitoring changes on the nano-scale in fine-grained materials in their natural wet state is demonstrated with a series of feasibility tests on well-controlled kaolin samples – that is, water content, pH and loading history. The results indicate that subtle changes on the nanometric…
12 March 2021
ApplicationCharacterizationCustomer publicationsGIWAXSInorganic materialInorganic materialsMaterialOtherOtherTechnique

Emergence of lead halide perovskite colloidal dispersions through aggregation and fragmentation: insights from the nanoscale to the mesoscale

Pratap, Shambhavi; Keller, Elisabeth; Müller-Buschbaum, Peter

The structural and optoelectronic properties of mixed halide perovskite colloidal precursor dispersions are investigated. With increasing concentration, we observe four stages of growing structures, which affect the thin film morphology: (I) nanoparticles, (II) increasing size of nanoparticles, (III) formation of large aggregates/complex clusters and (IV) fragmentation of large…
12 March 2021
ApplicationCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialPhase analysisPorous materialTechniqueWAXS

Synthesis and characterization of thermoresponsive [email protected] microgel composites with enhanced performance as an adsorption/release platform

Allegretto, Juan A.; Giussi, Juan M.; Moya, Sergio E.; Azzaroni, Omar; Rafti, Matias

Composite materials featuring a synergic combination of interesting properties such as stimuli responsiveness and tailored porosity are highly appealing due to their multiple possible applications. We hereby present an example which brings together such features by using poly(N-isopropyl-acrylamide)-derived thermo-responsive microgels and Zn-based Metal Organic Framework (MOF) ZIF-8, capable of…
12 March 2021
ApplicationCharacteristic dimensionCharacterizationCustomer publicationsInorganic materialsMaterialMetalsSAXSTechnique

Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions

S. Chang, Boyce; Thomas, Brijith; Chen, Jiahao; D. Tevis, Ian; Karanja, Paul; Çınar, Simge; Venkatesh, Amrit; J. Rossini, Aaron; M. Thuo, Martin

Coordination polymers are ideal synthons in creating high aspect ratio nanostructures, however, conventional synthetic methods are often restricted to batch-wise and costly processes. Herein, we demonstrate a non-traditional, frugal approach to synthesize 1D coordination polymers by in situ etching of zerovalent metal particle precursors. This procedure is denoted as the…
12 March 2021
ApplicationCharacteristic dimensionCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialTechniqueTemperatureWAXS

Solidification and melting phase change behavior of eutectic gallium-indium-tin

Koh, Amanda; Hwang, Wonseok; Y. Zavalij, Peter; Chun, Seth; Slipher, Geoffrey; Mrozek, Randy

The room-temperature liquid metal alloy of gallium, indium, and tin (galinstan) has been studied as a deformable conductive element for stretchable electronics and soft robotics. While these applications are predicated on the soft and conformable behavior of galinstan, little work has been done to understand the solidification of the liquid…
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialSAXSSelf-assembled materialShapeSizeTechnique

Gold and silver dichroic nanocomposite in the quest for 3D printing the Lycurgus cup

Kool, Lars; Dekker, Floris; Bunschoten, Anton; Smales, Glen J.; Pauw, Brian R.; Velders, Aldrik H.; Saggiomo, Vittorio

The Lycurgus cup is an ancient glass artefact that shows dichroism as it looks green when a white light is reflected on it and a red colouring appears when a white light is transmitted through it. This peculiar dichroic effect is due to silver and gold nanoparticles present in the…
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialSAXSSizeTechnique

Unprecedented Halide-Ion Binding and Catalytic Activity of Nanoscale Anionic Metal Oxide Clusters

She, Shan; Li, Mu; Li, Qi; Huang, Zehuan; Wei, Yongge; Yin, Panchao

One halide ion (X?) can bind on the surface of nanoscale Anderson-type polyoxometalate (POMs) clusters 3AlMo6O18(OH)3, and form stable complexes in solution with binding constant K=1.53×103. Single-crystal structural analysis showed that this binding behavior occurs through multiple hydrogen bonding between X? and three hydroxy groups on the uncapped side of…
5 March 2021
ApplicationCharacterizationCustomer publicationsGISAXSInorganic materialsMaterialMetalsOtherParticlesSurface structure and patternsTechnique

Ultrathin Homogenous AuNP Monolayers as Tunable Functional Substrates for Surface-Assisted Laser Desorption/Ionization of Small Biomolecules

Liu, Zhen; Zhang, Peng; Kister, Thomas; Kraus, Tobias; Volmer, Dietrich A.

A series of ultrathin, homogenous gold nanoparticle (AuNP) substrates for surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS) were prepared using a simple air/water interface approach. These SALDI substrates enabled soft ionization and provided significant improvements in terms of signal intensities and reduced background levels in comparison to other AuNP morphologies for…
27 January 2020
ApplicationCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialSAXSSpecific surfaceTechnique

Effect of the substrate temperature during gold-copper alloys thin film deposition by magnetron co-sputtering on the dealloying process

Chauvin, Adrien; Horak, Lukas; Duverger-Nédellec, Elen; Dopita, Milan; Tessier, Pierre-Yves; El Mel, Abdel-Aziz

Nanoporous gold is of great interest for many applications due to its three dimensional interconnected porosity at nanoscale. Among all currently use techniques to obtain nanoporous gold, dealloying is one of the most used method to create a well-controlled nanoporous morphology. Only few studies report on the creation of nanoporous…
27 January 2020