(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOtherSurface structure and patternsTechniqueThin films

Nano-confined crystallization of organic ultrathin nanostructure arrays with programmable geometries

Gao, Hanfei; Qiu, Yuchen; Feng, Jiangang; Li, Shuang; Wang, Huijie; Zhao, Yuyan; Wei, Xiao; Jiang, Xiangyu; Su, Yewang; Wu, Yuchen; Jiang, Lei

Fabricating ultrathin organic semiconductor nanostructures attracts wide attention towards integrated electronic and optoelectronic applications. However, the fabrication of ultrathin organic nanostructures with precise alignment, tunable morphology and high crystallinity for device integration remains challenging. Herein, an assembly technique for fabricating ultrathin organic single-crystal…
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisOtherSurface structure and patternsTechniqueThin films

Random Organic Nanolaser Arrays for Cryptographic Primitives

Feng, Jiangang; Wen, Wen; Wei, Xiao; Jiang, Xiangyu; Cao, Moyuan; Wang, Xuedong; Zhang, Xiqi; Jiang, Lei; Wu, Yuchen

Next-generation high-security cryptography and communication call for nondeterministic generation and efficient authentication of unclonable bit sequences. Physical unclonable functions using inherent randomness in material and device fabrication process have emerged as promising candidates for realizing one-way cryptographic systems that avoid duplication and attacks. However, previous…
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energyTechniqueThin films

Brønsted acid mediated covalent organic framework membranes for efficient molecular separation

Wang, Hongjian; Chen, Long; Yang, Hao; Wang, Meidi; Yang, Leixin; Du, Haiyan; Cao, Chenliang; Ren, Yanxiong; Wu, Yingzhen; Pan, Fusheng; Jiang, Zhongyi

Covalent organic frameworks (COFs) hold great promise in molecular separation. However, since the aperture size of most COFs is in the range of 0.8–4.9 nm, constructing COF membranes with a smaller aperture size is thus in urgent demand yet remains a grand challenge. In this study, a Brønsted acid mediated…
12 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisPolymer researchSurface structure and patternsTechniqueThin films

Controlling the pore size in conjugated polymer films via crystallization-driven phase separation

Guo, Shaowen; Lu, Yaguang; Wang, Binghua; Shen, Changyu; Chen, Jingbo; Reiter, Günter; Zhang, Bin

A wide range of possible applications in sensors and optoelectronic devices have focused considerable attention on porous membranes made of semi-conducting polymers. In this study, porous films of poly(3-hexylthiophene) (P3HT) were conveniently constructed through spin-coating of solutions of a blend of P3HT and polyethylene glycol (PEG). Pores were formed by…
12 March 2021
ApplicationCharacterizationCustomer publicationsFoodFood scienceGIWAXSLipidsMaterialPhase analysisSAXSSurface structure and patternsTechniqueWAXS

Physical Chemical Properties of Shea/Cocoa Butter Blends and their Potential for Chocolate Manufacture

Rodriguez-Negrette, Ana Carolina; Huck-Iriart, Cristián; Herrera, María Lidia

Cocoa butter (CB) is the preferred fat for chocolates and confections. However, for technological and economic reasons, there have been strong efforts for partially replacing it. As shea butter (SB) has become an important natural source of symmetrical stearic-rich triacylglycerols (TAG), the aim of this work was to study physical…
5 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisPolymer researchSurface structure and patternsTechniqueThin films

Synthesis and Solid-State Properties of PolyC3 (Co)polymers Containing (CH2–CH2–C(COOR)2) Repeat Units with Densely Packed Fluorocarbon Lateral Chains

Illy, Nicolas; Urayeneza, Deogratias; Maryasevskaya, Alina V.; Michely, Laurent; Boileau, Sylvie; Brissault, Blandine; Bersenev, Egor A.; Anokhin, Denis V.; Ivanov, Dimitri A.; Penelle, Jacques

The synthesis and structural characterization of linear PolyC3 polymers containing trimethylene-1,1-dicarboxylate structural repeat units with C6F13 and C8F17 fluorinated side chains is described for the first time, and their properties were compared with the traditional polyvinyl structures that display the fluorinated chain on every second rather than on every third…
5 March 2021
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOtherRenewable energySurface structure and patternsTechnique

Efficient Anti-solvent-free Spin-Coated and Printed Sn-Perovskite Solar Cells with Crystal-Based Precursor Solutions

He, Lintao; Gu, Hao; Liu, Xiaolong; Li, Pengwei; Dang, Yangyang; Liang, Chao; Ono, Luis K.; Qi, Yabing; Tao, Xutang

Tin-based perovskite solar cells (PSCs), with more consummate optical band gaps, lower exciton-binding energies, and higher charge-carrier mobility, have not attracted tremendous research efforts compared with the lead-based ones that have a record power conversion efficiency (PCE) of 24.2%. The major challenges for Sn-based research are significantly low open-circuit voltage,…
27 January 2020
(Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energyTechnique

Polyfluorene Copolymers as High-Performance Hole-Transport Materials for Inverted Perovskite Solar Cells

Hu, Jinlong; You, Jiang; Peng, Chang; Qiu, Shudi; He, Wenxin; Li, Chaohui; Liu, Xianhu; Mai, Yaohua; Guo, Fei

Inverted perovskite solar cells (PSCs) that can be entirely processed at low temperatures have attracted growing attention due to their cost-effective production. Hole-transport materials (HTMs) play an essential role in achieving efficient inverted PSCs, as they determine the effectiveness of charge extraction and recombination at interfaces. Herein, three polyfluorene copolymers…
27 January 2020
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisPhase analysisRenewable energySurface structure and patternsTechniqueThin films

Regulating the phase separation of ternary organic solar cells via 3D architectured AIE molecules

Adil, Muhammad Abdullah; Zhang, Jianqi; Wang, Yuheng; Yu, Jinde; Yang, Chen; Lu, Guanghao; Wei, Zhixiang

An optimized bulk heterojunction (BHJ) interface, certifying enhanced exciton-splitting, charge separation and recombination inhibition, is vastly desired to obtain high power conversion efficiencies (PCEs). Herein, the ternary strategy has been employed to effectively modify the phase separation between the J71:ITIC blend by incorporating a 3D aggregation-induced emission (AIE) material,…
27 January 2020
(Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSInorganic materialMaterialOrientation analysisPhase analysisPolymer researchSurface structure and patternsTechnique

How Confinement Affects the Nucleation, Crystallization, and Dielectric Relaxation of Poly(butylene succinate) and Poly(butylene adipate) Infiltrated within Nanoporous Alumina Templates

Safari, Maryam; Maiz, Jon; Shi, Guangyu; Juanes, Diana; Liu, Guoming; Wang, Dujin; Mijangos, Carmen; Alegría, Ángel; Müller, Alejandro J.

This work describes the successful melt infiltration of poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA) within 70 nm diameter anodic aluminum oxide (AAO) templates. The infiltrated samples were characterized by SEM, Raman, and FTIR spectroscopy. The crystallization behaviors and crystalline structures of both polymers, bulk and confined, were analyzed by…
27 January 2020