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GIWAXS

Charge carrier transport and nanomorphology control for efficient non-fullerene organic solar cells

Hu, Hanlin; Deng, Wanyuan; Qin, Minchao; Yin, Hang; Lau, Tsz-Ki; Fong, Patrick W. K.; Ren, Zhiwei; Liang, Qiong; Cui, Li; Wu, Hongbin; Lu, Xinhui; Zhang, Weimin; McCulloch, Iain; Li, Gang

 (Natural) polymersApplicationCharacterizationCustomer publicationsFractal dimensionGISAXSGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechniqueThin films

Charge carrier transport and nanomorphology control for efficient non-fullerene organic solar cells

Hu, Hanlin; Deng, Wanyuan; Qin, Minchao; Yin, Hang; Lau, Tsz-Ki; Fong, Patrick W. K.; Ren, Zhiwei; Liang, Qiong; Cui, Li; Wu, Hongbin; Lu, Xinhui; Zhang, Weimin; McCulloch, Iain; Li, Gang

Single junction organic photovoltaic devices (OPVs) have exceeded 15% power conversion efficiency (PCE) with the help of fused ring based low-bandgap non-fullerene acceptors (NFAs). As a major type of NFA, the indacenodithiophene derivative NFA (IDTBR) has been shown to have superior OPV stability with outstanding VOC, but the efficiency is…
ana.tutueanu@xenocs.com
25 November 2019
Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core

Yuan, Jun; Zhang, Yunqiang; Zhou, Liuyang; Zhang, Guichuan; Yip, Hin-Lap; Lau, Tsz-Ki; Lu, Xinhui; Zhu, Can; Peng, Hongjian; Johnson, Paul A.; Leclerc, Mario; Cao, Yong; Ulanski, Jacek; Li, Yongfang; Zou, Yingping

 (Natural) polymersApplicationCharacterizationCustomer publicationsFractal dimensionGISAXSGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechniqueThin films

Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core

Yuan, Jun; Zhang, Yunqiang; Zhou, Liuyang; Zhang, Guichuan; Yip, Hin-Lap; Lau, Tsz-Ki; Lu, Xinhui; Zhu, Can; Peng, Hongjian; Johnson, Paul A.; Leclerc, Mario; Cao, Yong; Ulanski, Jacek; Li, Yongfang; Zou, Yingping

Summary Recently, non-fullerene n-type organic semiconductors have attracted significant attention as acceptors in organic photovoltaics (OPVs) due to their great potential to realize high-power conversion efficiencies. The rational design of the central fused ring unit of these acceptor molecules is crucial to maximize device performance. Here, we report a new…
ana.tutueanu@xenocs.com
25 November 2019
Simply planarizing nonfused perylene diimide based acceptors toward promising non-fullerene solar cells

Bian, Gao-Feng; Zhao, Feng; Lau, Tsz-Ki; Sheng, Chun-Qi; Lu, Xinhui; Du, Hui; Zhang, Cheng; Qu, Zhi-Rong; Chen, Hongzheng; Wan, Jun-Hua

 (Natural) polymersApplicationCharacterizationCustomer publicationsFractal dimensionGISAXSGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechniqueThin films

Simply planarizing nonfused perylene diimide based acceptors toward promising non-fullerene solar cells

Bian, Gao-Feng; Zhao, Feng; Lau, Tsz-Ki; Sheng, Chun-Qi; Lu, Xinhui; Du, Hui; Zhang, Cheng; Qu, Zhi-Rong; Chen, Hongzheng; Wan, Jun-Hua

This work focuses on developing high-efficiency perylene diimide (PDI)-based small molecular nonfullerene acceptors with a simple synthetic strategy. We reported a new electron acceptor, Py-e-PDI, obtained via cross-coupling four PDI units with a planar pyrene core through ethynyl groups. Although the ring-fusion synthetic procedure was omitted, the large planar core…
ana.tutueanu@xenocs.com
25 November 2019
Improving the Stability and Monodispersity of Layered Cesium Lead Iodide Perovskite Thin Films by Tuning Crystallization Dynamics

Hadi, Atefe; Ryan, Bradley J.; Nelson, Rainie D.; Santra, Kalyan; Lin, Fang-Yi; Cochran, Eric W.; Panthani, Matthew G.

 ApplicationCharacterizationCustomer publicationsGIWAXSInorganic materialMaterialOrientation analysisRenewable energySurface structure and patternsTechnique

Improving the Stability and Monodispersity of Layered Cesium Lead Iodide Perovskite Thin Films by Tuning Crystallization Dynamics

Hadi, Atefe; Ryan, Bradley J.; Nelson, Rainie D.; Santra, Kalyan; Lin, Fang-Yi; Cochran, Eric W.; Panthani, Matthew G.

Assembling halide perovskites into layered structures holds promise for addressing chemical and phase stability challenges; however, several other challenges need to be addressed to create efficient and stable halide perovskite devices. Layered halide perovskites (LHPs) suffer from a broad distribution of layer thicknesses and band gaps within thin films. Reducing polydispersity…
ana.tutueanu@xenocs.com
25 November 2019
Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages

Cui, Yong; Yao, Huifeng; Zhang, Jianqi; Zhang, Tao; Wang, Yuming; Hong, Ling; Xian, Kaihu; Xu, Bowei; Zhang, Shaoqing; Peng, Jing; Wei, Zhixiang; Gao, Feng; Hou, Jianhui

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisRenewable energySurface structure and patternsTechnique

Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages

Cui, Yong; Yao, Huifeng; Zhang, Jianqi; Zhang, Tao; Wang, Yuming; Hong, Ling; Xian, Kaihu; Xu, Bowei; Zhang, Shaoqing; Peng, Jing; Wei, Zhixiang; Gao, Feng; Hou, Jianhui

Broadening the optical absorption of organic photovoltaic (OPV) materials by enhancing the intramolecular push-pull effect is a general and effective method to improve the power conversion efficiencies of OPV cells. However, in terms of the electron acceptors, the most common molecular design strategy of halogenation usually results in down-shifted molecular…
ana.tutueanu@xenocs.com
25 November 2019
Millimeter-Scale Unipolar Transport in High Sensitivity Organic–Inorganic Semiconductor X-ray Detectors

Jayawardena, K. D. G. Imalka; Thirimanne, Hashini M.; Tedde, Sandro Francesco; Huerdler, Judith E.; Parnell, Andrew J.; Bandara, R. M. Indrachapa; Mills, Christopher A.; Silva, S. Ravi P.

 (Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOtherPhase analysisSurface structure and patternsTechnique

Millimeter-Scale Unipolar Transport in High Sensitivity Organic–Inorganic Semiconductor X-ray Detectors

Jayawardena, K. D. G. Imalka; Thirimanne, Hashini M.; Tedde, Sandro Francesco; Huerdler, Judith E.; Parnell, Andrew J.; Bandara, R. M. Indrachapa; Mills, Christopher A.; Silva, S. Ravi P.

Hybrid inorganic-in-organic semiconductors are an attractive class of materials for optoelectronic applications. Traditionally, the thicknesses of organic semiconductors are kept below 1 μm due to poor charge transport in such systems. However, recent work suggests that charge carriers in such organic semiconductors can be transported over centimeter length scales opposing…
ana.tutueanu@xenocs.com
25 November 2019
5 nm Ordered Structures Self-Assembled by C2-Symmetric Hybrids with Polyhedral Oligomeric Silsesquioxane and Hexa-peri-Hexabenzocoronene.

Zhang, Wei; Pan, Hongbing; Lyu, Xiaolin; Gu, Kehua; Xiao, Anqi; Shen, Zhihao; Fan, Xing-he

 ApplicationCharacterizationCustomer publicationsGIWAXSInorganic materialsPhase analysisSurface structure and patternsTechniqueWAXS

5 nm Ordered Structures Self-Assembled by C2-Symmetric Hybrids with Polyhedral Oligomeric Silsesquioxane and Hexa-peri-Hexabenzocoronene.

Zhang, Wei; Pan, Hongbing; Lyu, Xiaolin; Gu, Kehua; Xiao, Anqi; Shen, Zhihao; Fan, Xing-he

Hybrids consisting of polyhedral oligomeric silsesquioxane (POSS) and hexa-peri-hexabenzocoronene (HBC) with a dumbbell topology and C2 symmetry were designed and synthesized. They self-assemble into 5 nm ordered structures. In particular, the increased steric effect with increasing POSS units stabilizes a square columnar phase (Colsqu) which is important in nanotemplating. These…
ana.tutueanu@xenocs.com
25 November 2019
A diketopyrrolopyrrole-based macrocyclic conjugated molecule for organic electronics

Li, Cheng; Wang, Chao; Guo, Yiting; Jin, Yingzhi; Yao, Nannan; Wu, Yonggang; Zhang, Fengling; Li, Weiwei

 (Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisPhase analysisRenewable energySurface structure and patternsTechnique

A diketopyrrolopyrrole-based macrocyclic conjugated molecule for organic electronics

Li, Cheng; Wang, Chao; Guo, Yiting; Jin, Yingzhi; Yao, Nannan; Wu, Yonggang; Zhang, Fengling; Li, Weiwei

The first diketopyrrolopyrrole based donor–acceptor macrocyclic conjugated molecule was developed and its application in organic electronics was systematically studied. , In this work, the first diketopyrrolopyrrole (DPP) based donor–acceptor macrocyclic conjugated molecule was developed and its application in organic electronics was systematically studied. Macrocyclic…
ana.tutueanu@xenocs.com
25 November 2019
An inverted planar solar cell with 13% efficiency and a sensitive visible light detector based on orientation regulated 2D perovskites

Lian, Xiaomei; Chen, Jiehuan; Fu, Ruilin; Lau, Tsz-Ki; Zhang, Yingzhu; Wu, Gang; Lu, Xinhui; Fang, Yanjun; Yang, Deren; Chen, Hongzheng

 (Natural) polymersApplicationCharacterizationCustomer publicationsGIWAXSMaterialOrientation analysisOtherRenewable energyTechnique

An inverted planar solar cell with 13% efficiency and a sensitive visible light detector based on orientation regulated 2D perovskites

Lian, Xiaomei; Chen, Jiehuan; Fu, Ruilin; Lau, Tsz-Ki; Zhang, Yingzhu; Wu, Gang; Lu, Xinhui; Fang, Yanjun; Yang, Deren; Chen, Hongzheng

Improving the film quality is of great importance in promoting the power conversion efficiency (PCE) of 2D perovskite-based solar cells (PVSCs), but the solution to this issue is limited. In this work, a strategy of combining the advantages of the ammonium thiocyanate (NH4SCN) additive and merged annealing (MA) process was…
ana.tutueanu@xenocs.com
18 July 2019
Cavitation-enabled rapid and tunable evolution of high-χN micelles as templates for ordered mesoporous oxides

Lokupitiya, Hasala N.; Stefik, Morgan

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsGISAXSGIWAXSMaterialOrientation analysisPolymer researchSizeTechniqueThin films

Cavitation-enabled rapid and tunable evolution of high-χN micelles as templates for ordered mesoporous oxides

Lokupitiya, Hasala N.; Stefik, Morgan

The kinetic-entrapment of block copolymer micelles enables size-persistence, however tuning micelle sizes under such conditions remains challenging. Agitation-induced chain exchange via vortexing is limited by the production of solution–air interfaces. Here, we use ultrasonic cavitation for rapid interface production that accelerates micelle growth by an order of magnitude over…
ana.tutueanu@xenocs.com
18 July 2019
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