The behavior of photochromic spiropyran (SP) dyes is greatly affected by the local environment in which they reside. Fluid microenvironments such as liquidlike polymers grant favorably fast dye decoloration whereas rigid microenvironments such as glassy polymers inhibit fast dye response. We study the use of disorganized but microphase-separated block polymer…
sergio.rodrigues@xenocs.com27 January 2020
In this work, we report on the synthesis of a series of polyesters based on 1,6-hexanediol, sebacic acid, and N,N’-dimethylene-bis(pyrrolidone-4-carboxylic acid) (BP-C2), of which the latter is derived from renewable itaconic acid and 1,2-ethanediamine. Copolymers with a varying amount of BP-C2 as dicarboxylic acid are synthesized using a melt-polycondensation reaction…
sergio.rodrigues@xenocs.com27 January 2020
The structure evolution and deformation behavior of tenter-frame biaxially oriented polyethylene (TF-BOPE) films were investigated in this study. For sequential biaxial stretching, the original spherulites were broken into small pieces, and the fibrillar structure simultaneously formed during the machine direction (MD) stretching. Subsequently, the single fibrils were pulled away, and…
sergio.rodrigues@xenocs.com27 January 2020
Building the desirable superstructure of polyethylene is one of the important topics for developing high value-added products, which brings potential benefits for society and sustainable development. Crystalline order is the ubiquitous superstructure for enhancing mechanical properties of polymeric materials. In this work, polystyrene copolymers (c-PS) are incorporated into pores of…
sergio.rodrigues@xenocs.com27 January 2020
The effect of solvent selectivity on the fragmentation kinetics of spherical micelles formed by a 1,2-polybutadiene-block-poly(ethylene oxide) BO copolymer in five 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide-based ionic liquids (ILs), (, where n = methyl, ethyl, butyl, hexyl, and octyl) was investigated by temperature-jump dynamic light scattering (T-jump DLS),
sergio.rodrigues@xenocs.com27 January 2020
Film rehydration method is commonly used for membrane protein (MP) reconstitution into block copolymer (BCP), but the lack of control in the rehydration step formed a heterogeneous population of proteopolymersomes that interferes with the characterization and performance of devices incorporating them. To improve the self-assembly of polymersomes with simultaneous MP…
sergio.rodrigues@xenocs.com27 January 2020
Tin-based perovskite solar cells (PSCs), with more consummate optical band gaps, lower exciton-binding energies, and higher charge-carrier mobility, have not attracted tremendous research efforts compared with the lead-based ones that have a record power conversion efficiency (PCE) of 24.2%. The major challenges for Sn-based research are significantly low open-circuit voltage,…
sergio.rodrigues@xenocs.com27 January 2020
Sensors are crucial in industrial robotics and smart production line owing to the basic needs for humanmachine communication and real-time monitoring. However, a lack of versatile sensing capability and multifunctionalities are still two urgent bottlenecks for current sensors to break through. In this study, from the biomimic perspective, helical and…
sergio.rodrigues@xenocs.com27 January 2020
A facile route for fabrication of polypropylene separators for lithium-ion batteries with high elongation and strong puncture resistance has been proposed in this work. Polypropylene separators immersed in paraffin wax have been prepared to introduce small molecules into separators. The influence of small molecules on mechanical properties of separators is…
sergio.rodrigues@xenocs.com27 January 2020
The microstructure of polyacrylonitrile (PAN)-based carbon fibers with different mechanical properties was investigated. It was found that the tensile strength of the PAN-based carbon fibers generally decrease with the increase in the modulus. The properties of PAN-based carbon fiber are mainly controlled by the microstructure and microvoids. The increase in…
sergio.rodrigues@xenocs.com27 January 2020