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Oil & gas

Enhancing the accessibility to basic sites of as-synthesized silicas applied in catalytic transesterification

Zapelini, Iago W.; Silva, Laura L.; Oliveira, Cristiano L. P.; Cardoso, Dilson

 ApplicationCharacterizationCustomer publicationsMaterialOil & gasParticle interactionsSAXSSurfactantsTechnique

Enhancing the accessibility to basic sites of as-synthesized silicas applied in catalytic transesterification

Zapelini, Iago W.; Silva, Laura L.; Oliveira, Cristiano L. P.; Cardoso, Dilson

Heterogeneous catalysis for biodiesel production is a current challenge due to the low activity of solid catalysts, especially caused by diffusional resistances. Hybrid silicas, containing SiO?CTA+ provide high conversions in the transesterification of oils and model molecules, but this activity is limited to the external surface area. The generation of…
ana.tutueanu@xenocs.com
27 January 2020
Rapid Stabilization of Immiscible Fluids using Nanostructured Interfaces via Surfactant Association

Niroobakhsh, Zahra; LaNasa, Jacob A.; Belmonte, Andrew; Hickey, Robert J.

 ApplicationCharacterizationCosmetics & consumer careCustomer publicationsMaterialOil & gasPhase analysisSAXSSurfactantsTechnique

Rapid Stabilization of Immiscible Fluids using Nanostructured Interfaces via Surfactant Association

Niroobakhsh, Zahra; LaNasa, Jacob A.; Belmonte, Andrew; Hickey, Robert J.

Surfactant molecules have been extensively used as emulsifying agents to stabilize immiscible fluids. Droplet stability has been shown to be increased when ordered nanoscale phases form at the interface of the two fluids due to surfactant association. Here, we report on using mixtures of a cationic surfactant and long chained…
ana.tutueanu@xenocs.com
27 January 2020
Synergistic Enhancement of CO2 Adsorption Capacity and Kinetics in Triethylenetetrammonium Nitrate Protic Ionic Liquid Functionalized SBA-15

Zhang, Wei; Gao, Erhao; Li, Yu; Bernards, Matthew T.; Li, Younan; Cao, Guanghan; He, Yi; Shi, Yao

 ApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialOil & gasPorous materialSAXSTechnique

Synergistic Enhancement of CO2 Adsorption Capacity and Kinetics in Triethylenetetrammonium Nitrate Protic Ionic Liquid Functionalized SBA-15

Zhang, Wei; Gao, Erhao; Li, Yu; Bernards, Matthew T.; Li, Younan; Cao, Guanghan; He, Yi; Shi, Yao

A series of triethylenetetrammonium nitrate protic ionic liquid (TNPIL) functionalized, highly ordered mesoporous SBA-15 molecular sieves with different loadings have been synthesized via impregnation. The CO2 capture performance of the hybrid sorbents was evaluated under conditions mimicking a combustion flue gas (15% CO2) over the temperature range of 298–348 K.…
ana.tutueanu@xenocs.com
27 January 2020
Partial Transformation of Imogolite by Decylphosphonic Acid Yields an Interface Active Composite Material

Lange, Tobias; Charpentier, Thibault; Gobeaux, Frédéric; Charton, Sophie; Testard, Fabienne; Thill, Antoine

 ApplicationCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialOil & gasPhase analysisSAXSTechnique

Partial Transformation of Imogolite by Decylphosphonic Acid Yields an Interface Active Composite Material

Lange, Tobias; Charpentier, Thibault; Gobeaux, Frédéric; Charton, Sophie; Testard, Fabienne; Thill, Antoine

The phosphonic acid moiety is commonly used as an anchoring group for the surface modification of imogolite. However, the impact of the reaction on its structure has never been clearly analyzed before. We study the reaction of imogolite and decylphosphonic acid by combining infrared spectroscopy, X-ray scattering, scanning electron microscopy,…
ana.tutueanu@xenocs.com
18 July 2019
Effects of calcination and activation conditions on ordered mesoporous carbon supported iron catalysts for production of lower olefins from synthesis gas

Oschatz, M.; Deelen, T. W. van; Weber, J. L.; Lamme, W. S.; Wang, G.; Goderis, B.; Verkinderen, O.; Dugulan, A. I.; Jong, K. P. de

 ApplicationCatalystsCharacterizationCustomer publicationsInorganic materialInorganic materialsMaterialOil & gasPhase analysisPorous materialSAXSTechnique

Effects of calcination and activation conditions on ordered mesoporous carbon supported iron catalysts for production of lower olefins from synthesis gas

Oschatz, M.; Deelen, T. W. van; Weber, J. L.; Lamme, W. S.; Wang, G.; Goderis, B.; Verkinderen, O.; Dugulan, A. I.; Jong, K. P. de

Lower C2–C4 olefins are important commodity chemicals usually produced by steam cracking of naphtha or fluid catalytic cracking of vacuum gas oil. The Fischer–Tropsch synthesis of lower olefins (FTO) with iron-based catalysts uses synthesis gas as an alternative feedstock. Nanostructured carbon materials are widely applied as supports for the iron…
Xenocs
12 March 2019
Study of liquid-phase molecular packing interactions and morphology of fatty acid methyl esters (biodiesel)

Berman, Paula; Meiri, Nitzan; Colnago, Luiz A.; Moraes, Tiago B.; Linder, Charles; Levi, Ofer; Parmet, Yisrael; Saunders, Michael; Wiesman, Zeev

 ApplicationCharacteristic dimensionCharacterizationCustomer publicationsLiquid crystalsMaterialOil & gasSAXSSelf-assembled materialTechnique

Study of liquid-phase molecular packing interactions and morphology of fatty acid methyl esters (biodiesel)

Berman, Paula; Meiri, Nitzan; Colnago, Luiz A.; Moraes, Tiago B.; Linder, Charles; Levi, Ofer; Parmet, Yisrael; Saunders, Michael; Wiesman, Zeev

Biotechnology for Biofuels, 2015, vol 8, 1, pp. 12DOI:10.1186/s13068-014-0194-7AbstractPMID: 25688289Visit the full articleBack to the overview
Xenocs
12 March 2019
Polymer-Grafted Nanoparticle Membranes with Controllable Free Volume

Bilchak, Connor R.; Buenning, Eileen; Asai, Makoto; Zhang, Kai; Durning, Christopher J.; Kumar, Sanat K.; Huang, Yucheng; Benicewicz, Brian C.; Gidley, David W.; Cheng, Shiwang; Sokolov, Alexei P.; Minelli, Matteo; Doghieri, Ferruccio

 (Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsMaterialNanoparticles & colloidsOil & gasParticlesPolymer researchPorous materialSAXSTechnique

Polymer-Grafted Nanoparticle Membranes with Controllable Free Volume

Bilchak, Connor R.; Buenning, Eileen; Asai, Makoto; Zhang, Kai; Durning, Christopher J.; Kumar, Sanat K.; Huang, Yucheng; Benicewicz, Brian C.; Gidley, David W.; Cheng, Shiwang; Sokolov, Alexei P.; Minelli, Matteo; Doghieri, Ferruccio

Polymer-based membranes play a key role in several industrially important gas separation technologies, e.g., removing CO2 from natural gas, with enormous economic and environmental impact. Here, we develop a novel hybrid membrane construct comprised entirely of nanoparticles grafted with polymers. These membranes are shown to have broadly tunable separation performance…
Xenocs
12 March 2019
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