Monthly Archives

March 2019

Customer publications

Assembly and photochemical properties of mesoporous networks of spinel ferrite nanoparticles for environmental photocatalytic remediation

Skliri, Euaggelia; Miao, Jianwei; Xie, Jian; Liu, Guangfeng; Salim, Teddy; Liu, Bin; Zhang, Qichun; Armatas, Gerasimos S.

Spinel ferrite materials have an electronic band structure that is well suited for visible light-induced catalysis, however, their photocatalytic activity remains low due to the daunting charge-carrier separation process. In this article, we report that high-surface-area mesoscopic architectures composed of tightly connected ultrasmall spinel ferrite nanocrystals can efficiently suppress…
Xenocs
12 March 2019
Customer publications

Are Keggin’s POMs Charged Nanocolloids or Multicharged Anions?

Malinenko, Alla; Jonchère, Alban; Girard, Luc; Parrès-Maynadié, Sandra; Diat, Olivier; Bauduin, Pierre

Owing to their multiple charges and their nanometric size, polyoxometalates (POMs) are at the frontier between ions and charged colloids. We investigated here the effect of POM–POM electrostatics repulsions on their self-diffusion in water by varying POM and supporting salt concentrations. The self-diffusion coefficients of two Keggin’s POMs [silicotungstate (SiW12O404–)…
Xenocs
12 March 2019
(Natural) polymersApplicationCharacteristic dimensionCharacterizationCustomer publicationsFractal dimensionMaterialPolymer researchSAXSTechniqueWAXS

Anomalies in the low frequency vibrational density of states for a polymer with intrinsic microporosity – the Boson peak of PIM-1

Zorn, Reiner; Yin, Huajie; Lohstroh, Wiebke; Harrison, Wayne; Budd, Peter M.; Pauw, Brian R.; Böhning, Martin; Schönhals, Andreas

Polymers with intrinsic microporosity are promising candidates for the active separation layer in gas separation membranes. Here, the vibrational density of states (VDOS) for PIM-1, the prototypical polymer with intrinsic microporosity, is investigated by means of inelastic neutron scattering. The results are compared to data measured for a more conventional…
Xenocs
12 March 2019
Customer publications

Acceleratory and inhibitory effects of uniaxial tensile stress on the photo-oxidation of polyethylene: Dependence of stress, time duration and temperature

Liu, Qiang; Yang, Heng; Zhao, Jincan; Liu, Shixiang; Xia, Lei; Hu, Ping; Lv, Yadong; Huang, Yajiang; Kong, Miqiu; Li, Guangxian

The photo-oxidation behavior of high density polyethylene (HDPE) subjected to uniaxial tensile stress is investigated at various temperatures, tensile stress levels and time durations. The effect of stress on the photo-oxidation rate of HDPE is found to be non-monotonous. Tensile stress is found to play distinctly different roles, namely showing…
Xenocs
12 March 2019
Customer publications

Aerogels of hierarchically porous syndiotactic polystyrene with a dielectric constant near to air

Joseph, Angel Mary; Nagendra, Baku; Shaiju, P.; Surendran, K. P.; Gowd, E. Bhoje

Herein ultralow density aerogels are developed through a feasible freeze casting technique. Briefly, the syndiotactic polystyrene (sPS) gel was prepared using xylene and subjected to successive steps of solvent exchange using non-solvents like ethanol and water. These samples were freeze-dried to obtain aerogels of the same shape and size as…
Xenocs
12 March 2019
Customer publications

A temperature-responsive supramolecular hydrogel: preparation, gel–gel transition and molecular aggregation

Wang, Lin; Shi, Xuefeng; Wang, Jinben

In this study, a novel supramolecular hydrogel, abbreviated as AGC16/NTS, was designed and constructed by the molecular self-assembly of a cationic gemini surfactant, 1,3-bis(N,N-dimethyl-N-cetylammonium)-2-propylacrylatedibromide (AGC16), and an anionic aromatic gelator, trisodium 1,3,6-naphthalenetrisulfonate (NTS). The AGC16/NTS hydrogel was able to form in a mass ratio range of AGC16 and NTS…
Xenocs
12 March 2019
Customer publications

A sumatriptan coarse-grained model to explore different environments: interplay with experimental techniques

Wood, Irene; Albano, Juan M. R.; Filho, Pedro L. O.; Couto, Veronica Muniz; de Farias, Marcelo A.; Portugal, Rodrigo V.; de Paula, Eneida; Oliveira, Cristiano L. P.; Pickholz, Monica

In this work, we developed a coarse-grained model of sumatriptan suitable for extensive molecular dynamics simulations. First, we confirmed the interfacial distribution of this drug in bilayers through cryogenic transmission electron microscopy and small-angle X-ray scattering techniques, as was predicted by our previous atomistic simulations. Based on these simulations, we…
Xenocs
12 March 2019
Customer publications

A multi-scale investigation on effects of hydrogen bonding on micro-structure and macro-properties in a polyurea

Li, Ting; Zhang, Cheng; Xie, Zhining; Xu, Jun; Guo, Bao-Hua

Effects of hydrogen bonding on the micro-structure development and mechanical properties of a bulk-polymerized Polyurea are systematically investigated from the perspective of temperatures. A two-stage temperature dependence of bidentate hydrogen bonding among hard domains, namely, slight dissociation from 85 °C to 165 °C and dramatic destruction above 165 °C, are revealed by Fourier…
Xenocs
12 March 2019