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Study of Iron-Bearing Dolomite Dissolution at Various Temperatures: Evidence for the Formation of Secondary Nanocrystalline Iron-Rich Phases on the Dolomite Surface

Debure, Mathieu; Andreazza, Pascal; Canizarès, Aurélien; Grangeon, Sylvain; Lerouge, Catherine; Mack, Paul; Madé, Benoît; Simon, Patrick; Veron, Emmanuel; Warmont, Fabienne; Vayer, Marylène

By 12 March 2019No Comments

ACS Earth and Space Chemistry, 2017, vol 1, 7, pp. 442-454



We investigated the dissolution of a natural Fe-containing dolomite [Ca1.003Mg0.972Fe0.024Mn0.002(CO3)2] under acidic conditions (pH 3–5.5) with atomic force microscopy (AFM) at 20 °C and with batch dissolution experiments at 80 °C. Dolomite dissolution proceeded by two identified mechanisms: removal of dolomite layers through spreading and coalescence of etch pits nucleated at defect points, and stepped retreat from surface edges. The dolomite dissolution rate increased when pH decreased (from 0.410 nm s–1 at pH 3 to 0.035 nm s–1 at pH 5). Rates calculated from edge retreat (vedges) and from etch-pit spreading rates (vsum) were consistent; the etch-pit digging rate was almost 10 times slower than its spreading rate. Nanocrystalline secondary phases precipitated in the course of dolomite dissolution at pH 3 and 80 °C were identified as (nano)hematite, ferrihydrite, and an ankerite like mineral using X-ray diffraction, transmission electron microscopy, MicroRaman and X-ray photoelectron spectrometry. In addition, Mg enrichment of the surface layer was observed at 80 °C. The characterizations performed at a nanocrystalline scale highlighted the role played by impurities in the dolomite dissolution/precipitation scheme and evidenced that the preponderant mechanism explaining the incongruent dolomite dissolution is secondary phase precipitation from major and minor elements initially present in the pristine dolomite.

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