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Hydrogen evolution at conjugated polymer nanoparticle electrodes

Fortin, Patrick; Rajasekar, Subash; Chowdhury, Pankaj; Holdcroft, Steven

By 12 March 2019July 18th, 2019No Comments

Canadian Journal of Chemistry, 2017, vol 96, 2, pp. 148-157

DOI:10.1139/cjc-2017-0329

Abstract

Organic polymer nanoparticles have been gaining attention in photovoltaics as a means to control the morphology of polymer composite films for the purpose of studying bulk heterojunction, photoactive layers. This work investigates the preparation of nanostructured organic thin films from P3HT:PC61BM nanoparticles and their characterization as photoelectrodes for the photoelectrochemical reduction of hydrogen in acidic solutions. The morphology and optoelectronic properties of the nanostructured photocathodes are compared with conventional, solution-cast thin films of P3HT:PC61BM. The nanostructured photoelectrodes provide increased surface area compared with solution-cast films through control of the nanoscale morphology within each nanoparticle, leading to enhanced P3HT:PC61BM phase segregation. The photo-assisted deposition of platinum nanoparticles as hydrogen evolution reaction (HER) catalysts onto the nanostructured P3HT:PC61BM photocathodes facilitates the photoreduction of protons to H2.

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