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Adsorption of sodium dodecylsulfate on single-walled carbon nanotubes characterised using small-angle neutron scattering

Kastrisianaki-Guyton, E. S.; Chen, L.; Rogers, S. E.; Cosgrove, T.; van Duijneveldt, J. S.

By 12 March 2019No Comments

Journal of Colloid and Interface Science, 2016, vol 472pp. 43472



Aqueous dispersions of single-walled carbon nanotubes are often made using sodium dodecylsulfate (SDS), which adsorbs to the nanotube surface to stabilise them. Despite SDS being commonly used with single-walled carbon nanotubes, there is no consensus on the structure of the adsorbed layer. Small-angle neutron and X-ray scattering results reported here show that the data can be fitted to a relatively simple core-shell cylinder model, consistent with a polydisperse nanotube core of radius 10 Å, surrounded by an adsorbed surfactant layer of thickness 18 Å and volume fraction of 0.5. This is consistent with small nanotube bundles surrounded by an adsorbed layer of extended SDS molecules.

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